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The haloform reaction can also occur inadvertently in domestic settings. Sodium hypochlorite solution (chlorine bleach) mixed with common household liquids such as acetone, methyl ethyl ketone, ethanol, or isopropyl alcohol can produce some chloroform, in addition to other compounds, such as chloroacetone or dichloroacetone. [citation needed]
In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.
Calcium chloride hexahydrate -40 1 to 0.8 ratio of salt to ice. Dry ice: Acetonitrile-41 Dry ice: Pyridine-42 Dry ice: Cyclohexanone-46 Dry ice: m-Xylene-47 Dry ice: Diethyl carbitol-52 Dry ice: n-Octane-56 Dry ice: Diisopropyl ether-60 Dry ice: Chloroform-61 Liquid N 2: Chloroform-63 [2] Dry ice: Ethanol-72 Note: without the addition of ...
A bath of ice and water will maintain a temperature 0 °C, since the melting point of water is 0 °C. However, adding a salt such as sodium chloride will lower the temperature through the property of freezing-point depression. Although the exact temperature can be hard to control, the weight ratio of salt to ice influences the temperature:
The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus. [citation needed] Chlorine adds to the multiple bonds on alkenes and alkynes as well, giving di- or tetra-chloro compounds. [citation needed]
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
In the laboratory, sodium formate can be prepared by neutralizing formic acid with sodium carbonate. It can also be obtained by reacting chloroform with an alcoholic solution of sodium hydroxide. CHCl 3 + 4 NaOH → HCOONa + 3 NaCl + 2 H 2 O. or by reacting sodium hydroxide with chloral hydrate. C 2 HCl 3 (OH) 2 + NaOH → CHCl 3 + HCOONa + H 2 O