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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
Gas chromatography (GC) is a common type of chromatography used in analytical chemistry for separating and analyzing compounds that can be vaporized without decomposition. Typical uses of GC include testing the purity of a particular substance, or separating the different components of a mixture. [ 1 ]
If column dimensions Length×diameter×film are divided by 2 and gas velocity is doubled by using H2 in place of Helium, the hold times must be divided by 4 and the ramps must be multiplied by 4 to keep the same index and the same retention temperature for the same compound analyzed. Method translation rules are incorporated in some ...
In engineering and physics, g c is a unit conversion factor used to convert mass to force or vice versa. [1] It is defined as = In unit systems where force is a derived unit, like in SI units, g c is equal to 1.
Volumetric flow rate is defined by the limit [3] = ˙ = =, that is, the flow of volume of fluid V through a surface per unit time t.. Since this is only the time derivative of volume, a scalar quantity, the volumetric flow rate is also a scalar quantity.
Unprimed quantities refer to position, velocity and acceleration in one frame F; primed quantities refer to position, velocity and acceleration in another frame F' moving at translational velocity V or angular velocity Ω relative to F. Conversely F moves at velocity (—V or —Ω) relative to F'. The situation is similar for relative ...
A key simplifying assumption Gurney made was that there is a linear velocity gradient in the explosive detonation product gases; in situations where this is strongly violated, such as implosions, the accuracy of the equations is low.
The vorticity equation of fluid dynamics describes the evolution of the vorticity ω of a particle of a fluid as it moves with its flow; that is, the local rotation of the fluid (in terms of vector calculus this is the curl of the flow velocity). The governing equation is: