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Tollens' reagent (chemical formula ()) is a chemical reagent used to distinguish between aldehydes and ketones along with some alpha-hydroxy ketones which can tautomerize into aldehydes. The reagent consists of a solution of silver nitrate , ammonium hydroxide and some sodium hydroxide (to maintain a basic pH of the reagent solution).
Unable to resist the call of his former professor Wöhler, Tollens returned to Göttingen in 1872 and there he remained in various positions until he died in 1918. It was during this final time in Göttingen that he started his work on carbohydrates, which yielded structures of several sugars, the Tollens' reagent, and most of his publications.
the central organic synthesis reagent for hydroboration Dicyclohexylcarbodiimide: an organic compound; primary use is to couple amino acids during artificial peptide synthesis Diethyl azodicarboxylate: a valuable reagent but also quite dangerous and explodes upon heating Diethyl ether: organic compound; a common laboratory solvent Dihydropyran
Reducing form of glucose (the aldehyde group is on the far right). A reducing sugar is any sugar that is capable of acting as a reducing agent. [1] In an alkaline solution, a reducing sugar forms some aldehyde or ketone, which allows it to act as a reducing agent, for example in Benedict's reagent.
In chemistry, a reagent (/ r i ˈ eɪ dʒ ən t / ree-AY-jənt) or analytical reagent is a substance or compound added to a system to cause a chemical reaction, or test if one occurs. [1] The terms reactant and reagent are often used interchangeably, but reactant specifies a substance consumed in the course of a chemical reaction. [ 1 ]
Phloroglucinol is a reagent of the Tollens' test for pentoses. This test relies on reaction of the furfural with phloroglucinol to produce a colored compound with high molar absorptivity. [26] A solution of hydrochloric acid and phloroglucinol is also used for the detection of lignin (Wiesner test).
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In organic chemistry, Fehling's solution is a chemical reagent used to differentiate between water-soluble carbohydrate and ketone (>C=O) functional groups, and as a test for reducing sugars and non-reducing sugars, supplementary to the Tollens' reagent test. The test was developed by German chemist Hermann von Fehling in 1849. [1]