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  2. Atomic orbital - Wikipedia

    en.wikipedia.org/wiki/Atomic_orbital

    To see the elongated shape of ψ(x, y, z) 2 functions that show probability density more directly, see pictures of d-orbitals below. In quantum mechanics, an atomic orbital (/ ˈ ɔːr b ɪ t ə l / ⓘ) is a function describing the location and wave-like behavior of an electron in an atom. [1]

  3. Delta bond - Wikipedia

    en.wikipedia.org/wiki/Delta_bond

    Formation of a δ bond by the overlap of two d orbitals 3D model of a boundary surface of a δ bond in Mo 2. In chemistry, a delta bond (δ bond) is a covalent chemical bond, in which four lobes of an atomic orbital on one atom overlap four lobes of an atomic orbital on another atom.

  4. Dewar–Chatt–Duncanson model - Wikipedia

    en.wikipedia.org/wiki/Dewar–Chatt–Duncanson...

    On the left, a filled pi-orbital on C 2 H 4 overlaps with an empty d-orbital on the metal. On the right, an empty pi-antibonding orbital on C 2 H 4 overlaps with a filled d-orbital on the metal The Dewar–Chatt–Duncanson model is a model in organometallic chemistry that explains the chemical bonding in transition metal alkene complexes .

  5. Azimuthal quantum number - Wikipedia

    en.wikipedia.org/wiki/Azimuthal_quantum_number

    Shape 0 s: sharp 2 Spherical (see this picture of spherical harmonics, top row). 1 p: principal 6 Three dumbbell-shaped polar-aligned orbitals; one lobe on each pole of the x, y, and z axes (on both + and − axes). 2 d: diffuse 10 Nine dumbbells and one doughnut, or "Unique shape #1" (see this picture of spherical harmonics, third row center). 3 f

  6. Square planar molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_planar_molecular...

    Representative d-orbital splitting diagrams for square planar complexes featuring σ-donor (left) and σ+π-donor (right) ligands. A general d-orbital splitting diagram for square planar (D 4h) transition metal complexes can be derived from the general octahedral (O h) splitting diagram, in which the d z 2 and the d x 2 −y 2 orbitals are degenerate and higher in energy than the degenerate ...

  7. Trigonal prismatic molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_prismatic...

    In chemistry, the trigonal prismatic molecular geometry describes the shape of compounds where six atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triangular prism. The structure commonly occurs for d 0, d 1 and d 2 transition metal complexes with covalently-bound ligands and small charge ...

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  9. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Some common shapes of simple molecules include: Linear: In a linear model, atoms are connected in a straight line. The bond angles are set at 180°. For example, carbon dioxide and nitric oxide have a linear molecular shape. Trigonal planar: Molecules with the trigonal planar shape are somewhat triangular and in one plane (flat). Consequently ...