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Another type of binary phase diagram is a boiling-point diagram for a mixture of two components, i. e. chemical compounds. For two particular volatile components at a certain pressure such as atmospheric pressure , a boiling-point diagram shows what vapor (gas) compositions are in equilibrium with given liquid compositions depending on temperature.
The phase space can also refer to the space that is parameterized by the macroscopic states of the system, such as pressure, temperature, etc. For instance, one may view the pressure–volume diagram or temperature–entropy diagram as describing part of this phase space. A point in this phase space is correspondingly called a macrostate.
In mathematics, a phase portrait is a geometric representation of the orbits of a dynamical system in the phase plane. Each set of initial conditions is represented by a different point or curve. Phase portraits are an invaluable tool in studying dynamical systems. They consist of a plot of typical trajectories in the phase space.
A generic phase diagram with unspecified axes; the invariant point is marked in red, metastable extensions labeled in blue, relevant reactions noted on stable ends of univariant lines. This rule is geometrically sound in the construction of phase diagrams since for every metastable reaction, there must be a phase that is relatively stable. This ...
The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some thermodynamic variable (such as temperature or pressure) leads to separation of the mixture into two ...
In water, the critical point occurs at around 647 K (374 °C or 705 °F) and 22.064 MPa. An unusual feature of the water phase diagram is that the solid–liquid phase line (illustrated by the dotted green line) has a negative slope. For most substances, the slope is positive as exemplified by the dark green line.
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
Phase diagram of water. On a pressure/temperature phase diagram (see figure), there are curves separating solid from vapor, vapor from liquid, and liquid from solid. These meet at a single point called the triple point, where all three phases can coexist.