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In scattering theory, the S-matrix is an operator mapping free particle in-states to free particle out-states (scattering channels) in the Heisenberg picture. This is very useful because often we cannot describe the interaction (at least, not the most interesting ones) exactly.
In S-matrix theory, it was stated that any quantity that one could measure should be found in the S-matrix for some process. This idea was inspired by the physical interpretation that S-matrix techniques could give to Feynman diagrams restricted to the mass-shell , and led to the construction of dual resonance models .
The following description follows the canonical way of introducing elementary scattering theory. A steady beam of particles scatters off a spherically symmetric potential V ( r ) {\displaystyle V(r)} , which is short-ranged, so that for large distances r → ∞ {\displaystyle r\to \infty } , the particles behave like free particles.
The Scattering transfer parameters or T-parameters of a 2-port network are expressed by the T-parameter matrix and are closely related to the corresponding S-parameter matrix. However, unlike S parameters, there is no simple physical means to measure the T parameters in a system, sometimes referred to as Youla waves.
Both the scattering and annihilation diagrams contribute to the transition matrix element. By letting k and k' represent the four-momentum of the positron, while letting p and p' represent the four-momentum of the electron, and by using Feynman rules one can show the following diagrams give these matrix elements:
The Kubo formula, named for Ryogo Kubo who first presented the formula in 1957, [1] [2] is an equation which expresses the linear response of an observable quantity due to a time-dependent perturbation.
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The functional attains stationary value equal to actual scattering T-matrix. The functional is stationary if and only if the two functions satisfy the Lippmann-Schwinger equation. The development of the variational formulation of the scattering theory can be traced to works of L. Hultén and J. Schwinger in 1940s. [1]