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This H 2 can then be used to hydrogenolyze the esters over a catalyst (e.g., copper chromite), [8] which are produced by esterifying either the ammonium carboxylate salts (e.g., ammonium acetate, propionate, butyrate) or the carboxylic acids (e.g., acetic, propionic, butyric acid) with a high-molecular-weight alcohol (e.g., hexanol, heptanol). [9]
Base-catalyzed transesterification reacts lipids (fats and oils) with alcohol (typically methanol or ethanol) to produce biodiesel and an impure coproduct, glycerol. [6] If the feedstock oil is used or has a high acid content, acid-catalyzed esterification can be used to react fatty acids with alcohol to produce biodiesel.
At large scale, ethyl acetoacetate is industrially produced by treatment of diketene with ethanol. [2] The small scale preparation of ethyl acetoacetate is a classic laboratory procedure. [3] It involves Claisen condensation of ethyl acetate. Two moles of ethyl acetate condense to form one mole each of ethyl acetoacetate and ethanol. [4]
Ethyl acetate (systematically ethyl ethanoate, commonly abbreviated EtOAc, ETAC or EA) is the organic compound with the formula CH 3 CO 2 CH 2 CH 3, simplified to C 4 H 8 O 2.This flammable, colorless liquid has a characteristic sweet smell (similar to pear drops) and is used in glues, nail polish removers, and the decaffeination process of tea and coffee.
Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a biofuel.
Distilling fermented products to yield alcoholic beverages with a high content by volume of ethyl alcohol. Desalination to produce potable water and for medico-industrial applications. Crude oil stabilisation , a partial distillation to reduce the vapor pressure of crude oil, which thus is safe to store and to transport, and thereby reduces the ...
The glyoxylate cycle can also provide plants with another aspect of metabolic diversity. This cycle allows plants to take in acetate both as a carbon source and as a source of energy. Acetate is converted to acetyl CoA (similar to the TCA cycle). This acetyl CoA can proceed through the glyoxylate cycle, and some succinate is released during the ...
The ABE fermentation pathway generally proceeds in two phases. In the initial acidogenesis phase, the cells grow exponentially and accumulate acetate and butyrate. The low pH along with other factors then trigger a metabolic shift to the solventogenesis phase, in which acetate and butyrate are used to produce the solvents. [4]