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Chromium(III) chloride (also called chromic chloride) is an inorganic chemical compound with the chemical formula Cr Cl 3. It forms several hydrates with the formula CrCl 3 · n H 2 O , among which are hydrates where n can be 5 (chromium(III) chloride pentahydrate CrCl 3 ·5H 2 O ) or 6 (chromium(III) chloride hexahydrate CrCl 3 ·6H 2 O ).
Solutions of metal aquo complexes are acidic owing to the ionization of protons from the water ligands. In dilute solution chromium(III) aquo complex has a pK a of about 4.3, affording a metal hydroxo complex: [Cr(H 2 O) 6] 3+ ⇌ [Cr(H 2 O) 5 (OH)] 2+ + H + Thus, the aquo ion is a weak acid, of comparable strength to acetic acid (pK a of about ...
The chromium atom is surrounded by six nitrogen atoms in an octahedral geometry. The NH 3 ligands are mutually trans and the Cr–NCS groups are linear. The salt crystallizes with one molecule of water. [1] It was first reported in 1863. [3]
Hexaamminecobalt(III) chloride is the chemical compound with the formula [Co(NH 3) 6]Cl 3. It is the chloride salt of the coordination complex [Co(NH 3 ) 6 ] 3+ , which is considered an archetypal "Werner complex", named after the pioneer of coordination chemistry, Alfred Werner .
Illustrative is the formation of chromium hexacarbonyl from anhydrous chromium(III) chloride in benzene with aluminum as a reducing agent, and aluminum chloride as the catalyst: [39] CrCl 3 + Al + 6 CO → Cr(CO) 6 + AlCl 3
CrCl 2 is produced by reducing chromium(III) chloride either with hydrogen at 500 °C: 2 CrCl 3 + H 2 → 2 CrCl 2 + 2 HCl. or by electrolysis. On the laboratory scale, LiAlH 4, zinc, and related reductants produce chromous chloride from chromium(III) precursors: 4 CrCl 3 + LiAlH 4 → 4 CrCl 2 + LiCl + AlCl 3 + 2 H 2 2 CrCl 3 + Zn → 2 CrCl 2 ...
Chromium(III) perchlorate is an inorganic compound, a salt with the chemical formula Cr(ClO 4) 3. It's hexahydrate Cr(ClO 4 ) 3 ·6H 2 O is a cyan solid that dissolves in water. Preparation
Cerium(III) chloride (CeCl 3), also known as cerous chloride or cerium trichloride, is a compound of cerium and chlorine. It is a white hygroscopic salt; it rapidly absorbs water on exposure to moist air to form a hydrate , which appears to be of variable composition, [ 1 ] though the heptahydrate CeCl 3 ·7H 2 O is known.