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Ethyl nitrate is the ethyl ester of nitric acid and has the chemical formula C 2 H 5 N O 3.It is a colourless, volatile, explosive, and extremely flammable liquid. It is used in organic synthesis with use as a nitrating agent and as an intermediate in the preparation of some drugs, dyes, and perfumes. [1]
Methemoglobinemia is the primary toxic effect of ethyl nitrite. [5] Due to ethyl nitrite's high volatility and faint smell, in the presence of ethyl nitrite vapors, it is easy to breath a high dose of it without realizing, resulting in methemoglobinemia, [6] which may or may not be severe, or even fatal.
Alkyl nitrites are also used in the formation of oximes with the stronger carbon acids and acid or base catalysis for example in the reaction of 2-butanone, ethyl nitrite and hydrochloric acid forming the oxime, [7] the similar reaction with phenacyl chloride, [8] or the reaction of phenylacetonitrile with methyl nitrite and sodium hydroxide. [9]
In organic chemistry, a nitrate ester is an organic functional group with the formula R−ONO 2, where R stands for any organyl group. They are the esters of nitric acid and alcohols . A well-known example is nitroglycerin , which is not a nitro compound, despite its name.
One of the main cetane improver additives manufactured today is 2-ethylhexyl nitrate (CAS n°: 27247-96-7) [1] which starts to decompose at 130 °C. 2-ethylhexyl nitrate is the result of the reaction of 2-ethylhexanol and nitric acid.
Esters of carboxylic acids with low molecular weight are commonly used as fragrances and found in essential oils and pheromones. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties, while polyesters are important plastics, with monomers linked by ester moieties.
Ethyl nitrite Ethyl nitrate: ... The Kornblum modification of this reaction uses sodium nitrite in either a dimethyl sulfoxide or dimethylformamide solvent. [6] Uses
Ethylammonium nitrate can be produced by heating ethyl nitrate with an alcoholic solution of ammonia [8] or by reacting ethylamine with concentrated nitric acid. [6] It has a relatively low viscosity of 0.28 poise or 0.028 Pa·s at 25 °C and therefore a high electrical conductivity of about 20 mS·cm −1 at 25 °C.