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A complete set of equations for the combustion of a hydrocarbon in the air, therefore, requires an additional calculation for the distribution of oxygen between the carbon and hydrogen in the fuel. The amount of air required for complete combustion is known as the "theoretical air" or "stoichiometric air". [3]
In real world applications, complete combustion does not typically occur. Chemistry dictates that dissociation and kinetics will change the composition of the products. There are a number of programs available that can calculate the adiabatic flame temperature taking into account dissociation through equilibrium constants (Stanjan, NASA CEA, AFTP).
The combustion of a stoichiometric mixture of fuel and oxidizer (e.g. two moles of hydrogen and one mole of oxygen) in a steel container at 25 °C (77 °F) is initiated by an ignition device and the reactions allowed to complete. When hydrogen and oxygen react during combustion, water vapor is produced.
Octane is a component of gasoline and petroleum. Under standard temperature and pressure, octane is an odorless, colorless liquid. Like other short-chained alkanes with a low molecular weight, it is volatile, flammable, and toxic. Octane is 1.2 to 2 times more toxic than heptane. [5]
A gasoline-fueled internal combustion engine obtains energy from the combustion of gasoline's various hydrocarbons with oxygen from the ambient air, yielding carbon dioxide and water as exhaust. The combustion of octane, a representative species, performs the chemical reaction: 2 C 8 H 18 + 25 O 2 → 16 CO 2 + 18 H 2 O
Air–fuel ratio (AFR) is the mass ratio of air to a solid, liquid, or gaseous fuel present in a combustion process. The combustion may take place in a controlled manner such as in an internal combustion engine or industrial furnace, or may result in an explosion (e.g., a dust explosion). The air–fuel ratio determines whether a mixture is ...
All alkanes react with oxygen in a combustion reaction, although they become increasingly difficult to ignite as the number of carbon atoms increases. The general equation for complete combustion is: C n H 2n+2 + ( 3 / 2 n + 1 / 2 ) O 2 → (n + 1) H 2 O + n CO 2 or C n H 2n+2 + ( 3n + 1 / 2 ) O 2 → (n + 1) H 2 O + n CO 2
This is illustrated in the image here, where the balanced equation is: CH 4 (g) + 2 O 2 (g) → CO 2 (g) + 2 H 2 O (l) Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of liquid water. This particular chemical equation is an example of complete combustion.