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Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures: log 10 (P) = −(0.05223)a/T + b, where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
There are two types of adiabatic flame temperature: constant volume and constant pressure, depending on how the process is completed. The constant volume adiabatic flame temperature is the temperature that results from a complete combustion process that occurs without any work, heat transfer or changes in kinetic or potential energy.
Methanol (also called methyl alcohol and wood spirit, amongst other names) is an organic chemical compound and the simplest aliphatic alcohol, with the chemical formula C H 3 OH (a methyl group linked to a hydroxyl group, often abbreviated as MeOH).
2 O,out is the number of moles of water vaporized and n fuel,in is the number of moles of fuel combusted. [9] Most applications that burn fuel produce water vapor, which is unused and thus wastes its heat content. In such applications, the lower heating value must be used to give a 'benchmark' for the process.
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Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
Methanol is far more difficult to ignite than gasoline and burns about 60% slower. A methanol fire releases energy at around 20% of the rate of a gasoline fire, resulting in a much cooler flame. This results in a much less dangerous fire that is easier to contain with proper protocols.
This high flame temperature is partially due to the absence of hydrogen in the fuel (dicyanoacetylene is not a hydrocarbon) thus there is no water among the combustion products. Cyanogen, with the formula (CN) 2, produces the second-hottest-known natural flame with a temperature of over 4,525 °C (8,177 °F) when it burns in oxygen. [11] [12]