Search results
Results From The WOW.Com Content Network
This is sometimes called the reverse water–gas shift reaction. [20] Water gas is defined as a fuel gas consisting mainly of carbon monoxide (CO) and hydrogen (H 2). The term 'shift' in water–gas shift means changing the water gas composition (CO:H 2) ratio. The ratio can be increased by adding CO 2 or reduced by adding steam to the reactor.
The water gas shift reaction is the reaction between carbon monoxide and steam to form hydrogen and carbon dioxide: CO + H 2 O ⇌ CO 2 + H 2. This reaction was discovered by Felice Fontana and nowadays is adopted in a wide range of industrial applications, such as in the production process of ammonia, hydrocarbons, methanol, hydrogen and other chemicals.
Steam can be added to the reaction in order to increase the generation of H 2, via the water-gas shift reaction (WGS) and/or steam methane reforming. The CLR process can produce a syngas with a H 2:CO molar ratio of 2:1 or higher, which is suitable for Fischer–Tropsch synthesis, methanol synthesis, or hydrogen production. The reduced oxygen ...
The gas mixture is cooled to 450 °C in a heat exchanger using water, freshly supplied gases, and other process streams. The ammonia also condenses and is separated in a pressure separator. Unreacted nitrogen and hydrogen are then compressed back to the process by a circulating gas compressor , supplemented with fresh gas, and fed to the ...
Water gas is a kind of fuel gas, a mixture of carbon monoxide and hydrogen. It is produced by "alternately hot blowing a fuel layer [coke] with air and gasifying it with steam". It is produced by "alternately hot blowing a fuel layer [coke] with air and gasifying it with steam".
A similar concept applies to liquid–gas phase changes. [7] Water is an exception which has a solid-liquid boundary with negative slope so that the melting point decreases with pressure. This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water.
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
Natural gas has a high hydrogen to carbon ratio, so the water-gas shift is not needed for cobalt catalysts. Cobalt-based catalysts are more sensitive than their iron counterparts. Illustrative of real world catalyst selection, high-temperature Fischer–Tropsch (HTFT), which operates at 330–350 °C, uses an iron-based catalyst.