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Bromine monofluoride is a quite unstable interhalogen compound with the chemical formula BrF. It can be produced through the reaction of bromine trifluoride (or bromine pentafluoride) and bromine. Due to its lability, the compound can be detected but not isolated: [2] BrF 3 + Br 2 → 3 BrF BrF 5 + 2 Br 2 → 5 BrF Br 2(l) + F 2(g) → 2 BrF (g)
Bromine fluoride may refer to several compounds with the elements bromine and fluorine: Bromine monofluoride, BrF;
A monofluoride is a chemical compound with one fluoride per formula unit. For a binary compound, this is the formula XF. ... Bromine monofluoride, a liquid ...
Chlorine monofluoride (ClF) is the lightest interhalogen compound. ClF is a colorless gas with a normal boiling point of −100 °C. Bromine monofluoride (BrF) has not been obtained as a pure compound — it dissociates into the trifluoride and free bromine. It is created according to the following equation: Br 2 (l) + F 2 (g) → 2 BrF(g)
While chlorine and bromine heptafluorides are not known, the corresponding cations ClF + 6 and BrF + 6, extremely strong oxidizers, are. [94] Astatine is not well-studied, and although there is a report of a non-volatile astatine monofluoride, [95] its existence is debated. [96] Many of the halogen fluorides are powerful fluorinators.
Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V ...
Bromotrifluoromethane is commercially synthesized in a two-step process from chloroform. Chloroform is fluorinated with hydrogen fluoride. [4] CHCl3 + 3 HF → CHF3 + 3 HCl The resulting Fluoroform is then reacted with elemental bromine. CHF3 + Br2 → CF3Br + HBr
4-Fluorobromobenzene is synthesized via bromination of fluorobenzene in the presence of a Lewis acid catalyst such as iron(III) bromide or aluminium tribromide. [2]4-Bromofluorobenzene is regarded by the Toxic Substances Control Act as a high production volume chemical, that is, a chemical that 1 million pounds (about 500 tonnes) per year is either produced in or imported to the United States.