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In organic chemistry, a ketone / ˈ k iː t oʊ n / is an organic compound with the structure R−C(=O)−R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group −C(=O)− (a carbon-oxygen double bond C=O). The simplest ketone is acetone (where R and R' are methyl), with the formula (CH 3) 2 CO ...
In chemistry, an acyl group is a moiety derived by the removal of one or more hydroxyl groups from an oxoacid, [1] including inorganic acids. It contains a double-bonded oxygen atom and an organyl group ( R−C=O ) or hydrogen in the case of formyl group ( H−C=O ).
In chemical nomenclature, the IUPAC nomenclature of organic chemistry is a method of naming organic chemical compounds as recommended [1] [2] by the International Union of Pure and Applied Chemistry (IUPAC). It is published in the Nomenclature of Organic Chemistry (informally called the Blue Book). [3]
For example, methanol has been shown to promote aryl migration. [11] [12] As shown below, if the reaction of piperanol (IV) with diazomethane is carried out in the absence of methanol, the ketone obtained though a hydride shift is the major product (V). If methanol is the solvent, an aryl shift occurs to form the aldehyde (VI), which cannot be ...
The equilibrium in water solution may be shifted towards either compound. For example, the equilibrium constant for the conversion of acetone (H 3 C) 2 C =O to propane-2,2-diol (H 3 C) 2 C(OH) 2 is about 10 −3, [1] while that of formaldehyde H 2 C =O to methanediol H 2 C(OH) 2 is 10 3. [2] For conversion of hexafluoroacetone (F 3 C) 2 C =O to ...
In ortho-substitution, two substituents occupy positions next to each other, which may be numbered 1 and 2.In the diagram, these positions are marked R and ortho.; In meta-substitution, the substituents occupy positions 1 and 3 (corresponding to R and meta in the diagram).
For example, an α-β, γ-δ unsaturated ketone can undergo a similar cationic conrotatory cyclization that is typically referred to as an iso-Nazarov cyclization reaction. [21] Other such extensions have been given similar names, including homo -Nazarov cyclizations and vinylogous Nazarov cyclizations.
The Stobbe condensation entails the reaction of an aldehyde or ketone with an ester of succinic acid to generate alkylidene succinic acid or related derivatives. [1] The reaction consumes one equivalent of metal alkoxide. Commonly, diethylsuccinate is a component of the reaction. The usual product is salt of the half-ester.