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The bleaching agent is either carbamide peroxide, which breaks down in the mouth to form hydrogen peroxide, or hydrogen peroxide itself. The bleaching gel typically contains between 10% and 44% carbamide peroxide, which is roughly equivalent to a 3% to 16% hydrogen peroxide concentration.
In the presence of a strong acid catalyst, such as sulfuric acid, acetic acid and hydrogen peroxide produce peracetic acid: [3] H 2 O 2 + CH 3 CO 2 H ⇌ CH 3 CO 3 H + H 2 O. However, in concentrations (3-6%) of vinegar and hydrogen peroxide marketed for household use, mixing without a strong acid catalyst will not form peracetic acid.