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Platinum is used as a catalyst for both half-reactions. This contributes to the loss of cell voltage potential, as any methanol that is present in the cathode chamber will oxidize. If another catalyst could be found for the reduction of oxygen, the problem of methanol crossover would likely be significantly lessened.
Hydrogen spillover can be characterized by three major steps, the first being where molecular hydrogen is split via dissociative chemisorption into its constitutive atoms on a transition metal catalyst surface, followed by migration from the catalyst to the substrate, culminating in their diffusion throughout the substrate surfaces and/or in ...
The monolith is a substrate that supports a catalyst. After the monolith is complete, a washcoat is applied that deposits oxides and catalyst(s) (most commonly platinum, palladium, and/or rhodium) on the walls of the holes. Alternative structures include corrugated metal and a packed bed of coated pellets or other shapes.
[3] [4] In this application, Rh–Pt oxide is superior to other group 10 catalysts such as platinum dioxide. Furthermore, the catalyst can be used to carry out the reaction with minimal losses of oxygen containing functional groups via hydrogenolysis .
Platinum black (Pt black) is a fine powder of platinum with good catalytic properties. The name of platinum black is due to its black color. It is used in many ways; as a thin film electrode, a fuel cell membrane catalyst, or as a catalytic ignition of flammable gases for "self-lighting' gas lamps, ovens, and stove burners.
Organoplatinum chemistry is the chemistry of organometallic compounds containing a carbon to platinum chemical bond, and the study of platinum as a catalyst in organic reactions. [ 1 ] [ 2 ] [ 3 ] Organoplatinum compounds exist in oxidation state 0 to IV, with oxidation state II most abundant.