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Atom economy. Atom economy (atom efficiency/percentage) is the conversion efficiency of a chemical process in terms of all atoms involved and the desired products produced. The simplest definition was introduced by Barry Trost in 1991 and is equal to the ratio between the mass of desired product to the total mass of reactants, expressed as a percentage.
The photosynthetic efficiency (i.e. oxygenic photosynthesis efficiency) is the fraction of light energy converted into chemical energy during photosynthesis in green plants and algae. Photosynthesis can be described by the simplified chemical reaction 6 H 2 O + 6 CO 2 + energy → C 6 H 12 O 6 + 6 O 2
As only R is the useful product, the atoms of X, Y and Z are said to be wasted as by-products. Economic and environmental costs of disposal of these waste make a reaction with low atom economy to be "less green". A further simplified version of this is the carbon economy. It is how much carbon ends up in the useful product compared to how much ...
The total reaction may be diffusion controlled (the electron transfer step is faster than diffusion, every encounter leads to reaction) or activation controlled (the "equilibrium of association" is reached, the electron transfer step is slow, the separation of the successor complex is fast). The ligand shells around A and D are retained.
Carbon on Earth naturally occurs in two stable isotopes, with 98.9% in the form of 12 C and 1.1% in 13 C. [1] [8] The ratio between these isotopes varies in biological organisms due to metabolic processes that selectively use one carbon isotope over the other, or "fractionate" carbon through kinetic or thermodynamic effects. [1]
Relationship of phosphate to nitrate uptake for photosynthesis in various regions of the ocean. Note that nitrate is more often limiting than phosphate. The Redfield ratio or Redfield stoichiometry is the consistent atomic ratio of carbon, nitrogen and phosphorus found in marine phytoplankton and throughout the deep oceans.
The CO 2 compensation point (Γ) is the CO 2 concentration at which the rate of photosynthesis exactly matches the rate of respiration. There is a significant difference in Γ between C 3 plants and C 4 plants: on land, the typical value for Γ in a C 3 plant ranges from 40–100 μmol/mol, while in C 4 plants the values are lower at 3–10 μmol/mol. Plants with a weaker CCM, such as C2 ...
Theoretically, it is easy to calculate ecological efficiency using the mathematical relationships above. It is often difficult, however, to obtain accurate measurements of the values involved in the calculation. Assessing ingestion, for example, requires knowledge of the gross amount of food consumed in an ecosystem as well as its caloric ...