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The stability fields of the Al 2 SiO 5 minerals polymorphs. 1, 2 and 3 are the stability fields of Kyanite, Andalusite and Sillimanite respectively. TP is the triple point, where, theoretically the three aluminosilicates minerals exist in equilibrium.
Own work using data from Whitney, D.L. (2002), “Coexisting andalusite, kyanite, and sillimanite: Sequential formation of three Al2SiO5 polymorphs during progressive metamorphism near the triple point, Sivrihisar, Turkey”, in American Mineralogist, volume 87, issue 4, pages 405–416
Kyanite. Andalusite. Sillimanite. Phase diagram of Al 2 SiO 5 (aluminosilicates). [1] Template documentation. Usage. Add {{Al2sio5 phase diagram}} to the page.
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite. [5]
Andalusite, kyanite, and sillimanite are the principal aluminium silicate minerals. [2] [3] [4] The triple point of the three polymorphs is located at a temperature of 500 °C (932 °F) and a pressure of 0.4 GPa (58,000 psi). These three minerals are commonly used as index minerals in metamorphic rocks.
An example is provided by the aluminium silicate minerals, kyanite, andalusite, and sillimanite. All three have the identical composition, Al 2 SiO 5. Kyanite is stable at surface conditions. However, at atmospheric pressure, kyanite transforms to andalusite at a temperature of about 190 °C (374 °F).
Figure 1. Petrogenetic grid for metapelites (several authors). [1] [2] Metamorphic facies included are: BS = Blueschist facies, EC = Eclogite facies, PP = Prehnite-Pumpellyite facies, GS = Granulite facies, EA = Epidote-Amphibolite facies, AM = Amphibolite facies, GRA = Granulite facies, UHT = Ultra-High Temperature facies, HAE = Hornfels-Albite-Epidote facies, Hbl = Hornblende-Hornfels facies ...
Andalusite is trimorphic with kyanite and sillimanite, being the lower pressure mid temperature polymorph. At higher temperatures and pressures, andalusite may convert to sillimanite. Thus, as with its other polymorphs, andalusite is an aluminosilicate index mineral, providing clues to depth and pressures involved in producing the host rock. [5]