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An acetate disc (also known as a lacquer, test acetate, dubplate, or transcription disc) is a type of phonograph record generally used from the 1930s to the late 1950s for recording and broadcast purposes. Despite their name, "acetate" discs do not contain any acetate. Lacquer-coated discs are used for the production of records.
The inductive effect acts like that for the carboxylate anion but in the opposite direction (i.e. it produces small positive charges on the ortho and para positions but not on the meta position and it destabilises the Wheland intermediate.) Hence these groups are deactivating and meta directing:
Groups with unshared pairs of electrons, such as the amino group of aniline, are strongly activating (some time deactivating also in case of halides) and ortho/para-directing by resonance. Such activating groups donate those unshared electrons to the pi system, creating a negative charge on the ortho and para positions.
In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group ( −CH 3 ) that is single-bonded to a carbonyl ( C=O ), making it an acyl group . The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter R ) of the ...
The ortho effect also occurs when a meta-directing group is positioned in a meta arrangement relative to an ortho–para-directing group, a new substituent introduced into the molecule tends to preferentially occupy the ortho position relative to the meta-directing group rather than the para position.
DMM copper disc sitting on the turntable of a Neumann AM32 lacquer cutting lathe, built in the 1930s. Direct metal mastering (DMM) is an analog audio disc mastering technique jointly developed by two German companies, Telefunken-Decca and Georg Neumann GmbH, toward the end of the 20th century after having seen the same technology used by RCA Princeton Labs for its SelectaVision videodiscs in ...
8. Buffalo Springfield. Before he became a successful solo act, Neil Young was a member of the folk-rock group Buffalo Springfield alongside Stephen Stills of Crosby, Stills, and Nash.
An acetate is a salt formed by the combination of acetic acid with a base (e.g. alkaline, earthy, metallic, nonmetallic or radical base). "Acetate" also describes the conjugate base or ion (specifically, the negatively charged ion called an anion) typically found in aqueous solution and written with the chemical formula C