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The kinetic theory of gases is a simple classical model of the thermodynamic behavior of gases. Its introduction allowed many principal concepts of thermodynamics to be established. Its introduction allowed many principal concepts of thermodynamics to be established.
A real world molecular system is unlikely to be present in vacuum. Jostling of solvent or air molecules causes friction, and the occasional high velocity collision will perturb the system. Langevin dynamics attempts to extend molecular dynamics to allow for these effects.
The kinetic theory of gases applies to the classical ideal gas, which is an idealization of real gases. In real gases, there are various effects (e.g., van der Waals interactions , vortical flow, relativistic speed limits, and quantum exchange interactions ) that can make their speed distribution different from the Maxwell–Boltzmann form.
Perhaps the greatest success of the kinetic theory of gases, as it came to be called, was the discovery that for gases, the temperature as measured on the Kelvin (absolute) temperature scale is directly proportional to the average kinetic energy of the gas molecules. Graham's law for diffusion could thus be understood as a consequence of the ...
The place of the Boltzmann kinetic equation on the stairs of model reduction from microscopic dynamics to macroscopic continuum dynamics (illustration to the content of the book [1]) The Boltzmann equation or Boltzmann transport equation ( BTE ) describes the statistical behaviour of a thermodynamic system not in a state of equilibrium ; it was ...
Kinetic theory may refer to: Kinetic theory of matter: A general account of the properties of matter, including solids liquids and gases, based around the idea that heat or temperature is a manifestation of atoms and molecules in constant agitation. Kinetic theory of gases, an account of gas properties in terms of motion and interaction of ...
At the molecular level, gas dynamics is a study of the kinetic theory of gases, often leading to the study of gas diffusion, statistical mechanics, chemical thermodynamics and non-equilibrium thermodynamics. [2] Gas dynamics is synonymous with aerodynamics when the gas field is air and the subject of study is flight.
Chapman–Enskog theory also predicts a simple relation between thermal conductivity, , and viscosity, , in the form =, where is the specific heat at constant volume and is a purely numerical factor. For spherically symmetric molecules, its value is predicted to be very close to 2.5 {\displaystyle 2.5} in a slightly model-dependent way.