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Latent heat is energy released or absorbed by a body or a thermodynamic system during a constant-temperature process. Two common forms of latent heat are latent heat of fusion and latent heat of vaporization . These names describe the direction of energy flow when changing from one phase to the next: from solid to liquid, and liquid to gas.
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
Molar specific heat capacity (isochoric) C nV = / J⋅K⋅ −1 mol −1: ML 2 T −2 Θ −1 N −1: Specific latent heat: L = / J⋅kg −1: L 2 T −2: Ratio of isobaric to isochoric heat capacity, heat capacity ratio, adiabatic index, Laplace coefficient
Substituting into the Clapeyron equation =, we can obtain the Clausius–Clapeyron equation [8]: 509 = for low temperatures and pressures, [8]: 509 where is the specific latent heat of the substance. Instead of the specific, corresponding molar values (i.e. L {\displaystyle L} in kJ/mol and R = 8.31 J/(mol⋅K)) may also be used.
Enthalpies of melting and boiling for pure elements versus temperatures of transition, demonstrating Trouton's rule. In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure.
It also allows us to determine the specific volume of a saturated vapor and liquid at that provided temperature. In the equation below, represents the specific latent heat, represents temperature, and represents the change in specific volume. [3]
Specific heat capacity often varies with temperature, and is different for each state of matter. Liquid water has one of the highest specific heat capacities among common substances, about 4184 J⋅kg −1 ⋅K −1 at 20 °C; but that of ice, just below 0 °C, is only 2093 J⋅kg −1 ⋅K −1.
The Stefan number [1] (St or Ste) is defined as the ratio of sensible heat to latent heat.It is given by the formula =, where c p is the specific heat, . c p is the specific heat of solid phase in the freezing process while c p is the specific heat of liquid phase in the melting process.