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In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". [ 1 ] [ 2 ] The solid formed is called the precipitate . [ 3 ] In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant .
In chemistry, coprecipitation (CPT) or co-precipitation is the carrying down by a precipitate of substances normally soluble under the conditions employed. [1] Analogously, in medicine, coprecipitation (referred to as immunoprecipitation) is specifically "an assay designed to purify a single antigen from a complex mixture using a specific antibody attached to a beaded support".
The precipitate that forms a band is not always a binary insoluble compound, but may be even a pure metal. Water glass of density 1.06 made acidic by sufficient acetic acid to make it gel, with 0.05 N copper sulfate in it, covered by a 1 percent solution of hydroxylamine hydrochloride produces large tetrahedrons of metallic copper in the bands.
Classically, these reactions result in the precipitation of one product. In older literature, the term double decomposition is common. The term double decomposition is more specifically used when at least one of the substances does not dissolve in the solvent , as the ligand or ion exchange takes place in the solid state of the reactant.
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Ammonium sulfate is an inorganic salt with a high solubility that disassociates into ammonium (NH + 4) and sulfate (SO 2− 4) in aqueous solutions. [1] Ammonium sulfate is especially useful as a precipitant because it is highly soluble, stabilizes protein structure, has a relatively low density, is readily available, and is relatively inexpensive.
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A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.