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Danishefsky Taxol total synthesis overview from raw material perspective. The Danishefsky Taxol total synthesis in organic chemistry is an important third Taxol synthesis published by the group of Samuel Danishefsky in 1996 [1] two years after the first two efforts described in the Holton Taxol total synthesis and the Nicolaou Taxol total synthesis.
Samuel J. Danishefsky was born in 1936 in the United States.He completed his B.S. from Yeshiva University in 1956. He earned his Ph.D. in chemistry from Harvard University in 1962 with Peter Yates, which partially overlapped with a National Institutes of Health postdoctoral fellowship in the laboratory of Gilbert Stork at Columbia University.
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Danishefsky utilized this methodology for the synthesis of taxol. Diastereoselectivity is established by 1,3 interactions in the transition state required for epoxide closure. [54] corey-chaykovsky total synthesis example