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  2. Non-bonding orbital - Wikipedia

    en.wikipedia.org/wiki/Non-bonding_orbital

    An example of a non-similar one is the non-bonding orbital of the allyl anion, whose electron density is concentrated on the first and third carbon atoms. [ 1 ] In fully delocalized canonical molecular orbital theory, it is often the case that none of the molecular orbitals of a molecule are strictly non-bonding in nature.

  3. 18-electron rule - Wikipedia

    en.wikipedia.org/wiki/18-electron_rule

    Compounds that obey the 18-electron rule are typically "exchange inert". Examples include [Co(NH 3) 6]Cl 3, Mo(CO) 6, and [Fe(CN) 6] 4−.In such cases, in general ligand exchange occurs via dissociative substitution mechanisms, wherein the rate of reaction is determined by the rate of dissociation of a ligand.

  4. Periodic table - Wikipedia

    en.wikipedia.org/wiki/Periodic_table

    Periodic table of the chemical elements showing the most or more commonly named sets of elements (in periodic tables), and a traditional dividing line between metals and nonmetals. The f-block actually fits between groups 2 and 3 ; it is usually shown at the foot of the table to save horizontal space.

  5. Lone pair - Wikipedia

    en.wikipedia.org/wiki/Lone_pair

    Examples are the transition metals where the non-bonding pairs do not influence molecular geometry and are said to be stereochemically inactive. In molecular orbital theory (fully delocalized canonical orbitals or localized in some form), the concept of a lone pair is less distinct, as the correspondence between an orbital and components of a ...

  6. Localized molecular orbitals - Wikipedia

    en.wikipedia.org/wiki/Localized_molecular_orbitals

    In the water molecule for example, ab initio calculations show bonding character primarily in two molecular orbitals, each with electron density equally distributed among the two O-H bonds. The localized orbital corresponding to one O-H bond is the sum of these two delocalized orbitals, and the localized orbital for the other O-H bond is their ...

  7. List of chemical elements - Wikipedia

    en.wikipedia.org/wiki/List_of_chemical_elements

    Like the periodic table, the list below organizes the elements by the number of protons in their atoms; it can also be organized by other properties, such as atomic weight, density, and electronegativity. For more detailed information about the origins of element names, see List of chemical element name etymologies.

  8. Octet rule - Wikipedia

    en.wikipedia.org/wiki/Octet_rule

    The bonding in carbon dioxide (CO 2): all atoms are surrounded by 8 electrons, fulfilling the octet rule.. The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas.

  9. Periodic table (electron configurations) - Wikipedia

    en.wikipedia.org/wiki/Periodic_table_(electron...

    The construction of the periodic table ignores these irregularities and is based on ideal electron configurations. [2] Note the non-linear shell ordering, which comes about due to the different energies of smaller and larger shells.

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