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Cobalt complex HCo(CO) 4 with five ligands. In coordination chemistry, a ligand [a] is an ion or molecule with a functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis bases. [1]
Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...
In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. [1] The ligand may be atomic or polyatomic. Virtually all complex organic compounds can serve as bridging ligands, so the term is usually restricted to small ligands such as pseudohalides or to ligands that are specifically designed to ...
These ligands, which tend to engage in intramolecular hydrogen bonds. Illustrative is the complex derived from dimethylphosphine oxide, PtH(PMe 2 OH) 2 (PMe 2 O) (Me = CH 3). [9] The pattern also applies to several phosphorus compounds including phosphorous acid, which forms complexes as P(OH) 3. The complex platinum pop is one example.
For simple carboxylates, the acetate complexes are illustrative. Most transition metal acetates are mixed ligand complexes. One common example is hydrated nickel acetate, Ni(O 2 CCH 3) 2 (H 2 O) 4, which features intramolecular hydrogen-bonding between the uncoordinated oxygens and the protons of aquo ligands. Stoichiometrically simple ...
In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond [3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]
In some compounds the metal-ligand bonds may not all be at the same distance. For example in PbCl 2, the coordination number of Pb 2+ could be said to be seven or nine, depending on which chlorides are assigned as ligands. Seven chloride ligands have Pb-Cl distances of 280–309 pm.
Phosphate binds to metals through one, two, three, or all four oxygen atoms. The bidentate coordination mode is common. The second and third pK a 's of phosphoric acid, pK a2 and pK a3, are 7.2 and 12.37, respectively. It follows that HPO 2− 4 and PO 3− 4 are sufficiently basic to serve as ligands. The examples below confirm this expectation.