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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
C is the coefficient of thermal expansion of the metal that forms the tape; L is the length of the tape or length of the line measured. is the observed temperature of the tape at the time of measurement; is the standard temperature, when the tape is at the correct length, often 20 °C;
The Heaviside cover-up method, named after Oliver Heaviside, is a technique for quickly determining the coefficients when performing the partial-fraction expansion of a rational function in the case of linear factors. [1] [2] [3] [4]
This provides an expression for the Joule–Thomson coefficient in terms of the commonly available properties heat capacity, molar volume, and thermal expansion coefficient. It shows that the Joule–Thomson inversion temperature, at which μ J T {\displaystyle \mu _{\mathrm {JT} }} is zero, occurs when the coefficient of thermal expansion is ...
While volume is a three dimensional parameter, thermal changes can be modeled in a single dimension with linear expansion, assuming an adequately small temperature range. For examples, glass manufacturer Schott provides the coefficient of linear thermal expansion for a temperature range of -30 C to 70 C.
This concept lies in the basis for the kinetic theory of matter and thermal expansion of matter, which states as the temperature of a substance rises, so does the average kinetic energy of its molecules. As such, a rise in kinetic energy requires more space between the particles of a given substance, which leads to its physical expansion. [2]
Therefore, the sign of thermal expansion coefficient is determined by the sign of the third derivative of the potential. In multidimensional case the geometrical nonlinearity is also present, i.e. lattice vibrations are nonlinear even in the case of harmonic interatomic potential. This nonlinearity contributes to thermal expansion.
where γ is the heat capacity ratio, α is the volumetric coefficient of thermal expansion, ρ = N/V is the particle density, and = (/) is the thermal pressure coefficient. In an extensive thermodynamic system, the application of statistical mechanics shows that the isothermal compressibility is also related to the relative size of fluctuations ...