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The active isomer of deltamethrin, (1R)-cis-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylic acid, has the same stereochemistry. γ-cyhalothrin (a single chiral isomer) is indeed twice as active as λ-cyhalothrin on a weight-for-weight basis. The latter is racemic and contains the (1R) and inactive (1S) isomers in equal amounts.
The resmethrin molecule has four stereoisomers determined by cis-trans orientation around a carbon triangle and chirality. Technical resmethrin is a mixture of (1R,trans)-, (1R,cis)-, (1S,trans)-, and (1S,cis)- isomers, typically in a ratio of 4:1:4:1. The 1R isomers (both trans and cis) show strong insecticidal activity, while the 1S isomers ...
Cyfluthrin is a pyrethroid insecticide and common household pesticide. It is a complex organic compound and the commercial product is sold as a mixture of isomers.Like most pyrethroids (MoA 3a), [1] it is highly toxic to fish and invertebrates, but it is far less toxic to humans. [2]
One of the four stereoisomers, (1R,3R)- or (+)-trans-chrysanthemic acid (pictured), is the acid part of the ester pyrethrin I, which occurs naturally in the seed cases of Chrysanthemum cinerariaefolium. Many synthetic pyrethroids, for example the allethrins, are esters of all four stereoisomers. [1]
Because (1R,3R)-1,2,3-trimethylcyclopentane is a cycloalkane, its three methyl substituents are capable of exhibiting cis/trans isomerism. This implies that the methyl groups in positions 1,2, and 3 may occupy different spatial arrangements (i.e.they may either lay cis or trans with respect to each other).
Tefluthrin (X=CH 3) is manufactured by the esterification of cyhalothrin acid chloride [6] with 4-methyl-2,3,5,6-tetrafluorobenzyl alcohol. [7] The latter was a novel compound when tefluthrin was invented [ 8 ] and the choice of routes to it has been discussed.
trans-1,2-Diaminocyclohexane is an organic compound with the formula C 6 H 10 (NH 2) 2.This diamine is a building block for C 2-symmetric ligands that are useful in asymmetric catalysis.
meso-Stilbene dibromide is an organic compound with a formula of (C 6 H 5 CH(Br)) 2. [3] It is one of three isomeric stilbene dibromides, the others being the pair of enantiomers. All are white solids. [4]