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The Cr 2 (OAc) 4 (H 2 O) 2 molecule contains two atoms of chromium, two ligated molecules of water, and four acetate bridging ligands.The coordination environment around each chromium atom consists of four oxygen atoms (one from each acetate ligand) in a square, one water molecule (in an axial position), and the other chromium atom (opposite the water molecule), giving each chromium centre an ...
The anhydrous solid is white when pure, however commercial samples are often grey or green; it is hygroscopic and readily dissolves in water to give bright blue air-sensitive solutions of the tetrahydrate Cr(H 2 O) 4 Cl 2. Chromium(II) chloride has no commercial uses but is used on a laboratory-scale for the synthesis of other chromium complexes.
The pentahydrate CrSO 4 ·5H 2 O is a blue solid that dissolves readily in water. Solutions of chromium(II) are easily oxidized by air to Cr(III) species. Solutions of Cr(II) are used as specialized reducing agents of value in organic synthesis. [1] The salt is produced by treating chromium metal with aqueous sulfuric acid: [2]
Chromium(II) carbide (Cr 3 C 2) Chromium(II) compounds are uncommon, in part because they readily oxidize to chromium(III) derivatives in air. Water-stable chromium(II) chloride CrCl 2 that can be made by reducing chromium(III) chloride with zinc. The resulting bright blue solution created from dissolving chromium(II) chloride is stable at ...
It is a name reaction, named for Kazuhiko Takai, who first reported it in 1986. [1] In the original reaction, the organochromium species is generated from iodoform or bromoform and an excess of chromium(II) chloride and the product is a vinyl halide. One main advantage of this reaction is the E-configuration of the double bond that is formed.
Chromium(II) sulfide may be formed by reaction of chromium metal with sulfur or hydrogen sulfide at high temperature. It may also be formed by reacting chromium(III) chloride with H 2 S, reducing chromium(III) sulfide with hydrogen, or by double replacement reaction of lithium sulfide with chromium(II) chloride. [5]
Chromium(II) ion in aqueous solution. Most aquo complexes are mono-nuclear, with the general formula [M(H 2 O) 6] n+, with n = 2 or 3; they have an octahedral structure. The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond with it. Typical examples are listed in the ...
According to Nikumbh et al., CrC 2 O 4 ·2H 2 O can be prepared from chromium(II) sulfate pentahydrate by reaction with a mixture of sodium oxalate and oxalic acid in degassed aqueous solution, forming a light green crystalline product, which has been characterized by combustion elemental analysis, infrared spectroscopy, thermogravimetric analysis and powder X-ray diffraction. [1]