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Formaldehyde is readily oxidized by atmospheric oxygen into formic acid. For this reason, commercial formaldehyde is typically contaminated with formic acid. Formaldehyde can be hydrogenated into methanol. In the Cannizzaro reaction, formaldehyde and base react to produce formic acid and methanol, a disproportionation reaction.
In organic chemistry, the Mannich reaction is a three-component organic reaction that involves the amino alkylation of an acidic proton next to a carbonyl (C=O) functional group by formaldehyde (H−CHO) and a primary or secondary amine (−NH 2) or ammonia (NH 3). [1] The final product is a β-amino-carbonyl compound also known as a Mannich base.
Industrially, formaldehyde is produced by catalytic oxidation of methanol. The most commonly used catalysts are silver metal or a mixture of an iron oxide with molybdenum and/or vanadium . In the recently more commonly used Formox process using iron oxide and molybdenum and/or vanadium, methanol and oxygen react at 300-400°C to produce ...
Formaldehyde is produced industrially by oxidative dehydrogenation of methanol. This reaction can also be viewed as a dehydrogenation using O 2 as the acceptor. The most common catalysts are silver metal, iron(III) oxide , [ 7 ] iron molybdenum oxides [e.g. iron(III) molybdate ] with a molybdenum -enriched surface, [ 8 ] or vanadium oxides .
The Eschweiler–Clarke reaction (also called the Eschweiler–Clarke methylation) is a chemical reaction whereby a primary (or secondary) amine is methylated using excess formic acid and formaldehyde. [1] [2] Reductive amination reactions such as this one will not produce quaternary ammonium salts, but instead will stop at the tertiary amine ...
With water and a protic acid such as sulfuric acid as the reaction medium and formaldehyde the reaction product is a 1,3-diol (3). When water is absent, the cationic intermediate loses a proton to give an allylic alcohol (4). With an excess of formaldehyde and a low reaction temperature the reaction product is a dioxane (5).
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Tröger's base [1] is a white solid tetracyclic organic compound. [2] Its chemical formula is (CH 3 C 6 H 3 NCH 2) 2 CH 2. Tröger's base and its analogs are soluble in various organic solvents and strong acidic aqueous solutions due to their protonation. It is named after Julius Tröger, who first synthesized it in 1887.