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A galvanic anode, or sacrificial anode, is the main component of a galvanic cathodic protection system used to protect buried or submerged metal structures from corrosion. They are made from a metal alloy with a more "active" voltage (more negative reduction potential / more positive oxidation potential ) than the metal of the structure.
Over time the galvanic anode continues to corrode, consuming the anode material until eventually it must be replaced. Galvanic or sacrificial anodes are made in various shapes and sizes using alloys of zinc, magnesium, and aluminum. ASTM International publishes standards on the composition and manufacturing of galvanic anodes. [10] [11] [12]
Anodic protection (AP) otherwise referred to as Anodic Control is a technique to control the corrosion of a metal surface by making it the anode of an electrochemical cell and controlling the electrode potential in a zone where the metal is passive.
Sacrificial metals are widely used to prevent other metals from corroding: for example in galvanised steel. [3] Many steel objects are coated with a layer of zinc, which is more electronegative than iron, and thus oxidises in preference to the iron, preventing the iron from rusting. [4]
In this case, sacrificial anodes work as part of a galvanic couple, promoting corrosion of the anode, while protecting the cathode metal. In other cases, such as mixed metals in piping (for example, copper, cast iron and other cast metals), galvanic corrosion will contribute to accelerated corrosion of parts of the system.
The galvanic series (or electropotential series) determines the nobility of metals and semi-metals. When two metals are submerged in an electrolyte, while also electrically connected by some external conductor, the less noble (base) will experience galvanic corrosion. The rate of corrosion is determined by the electrolyte, the difference in ...
The corrosion protection is primarily due to the anodic potential dissolution of zinc versus iron. Zinc acts as a sacrificial anode for protecting iron (steel). While steel is close to -400 mV, depending on alloy composition, electroplated zinc is much more anodic with -980 mV. Steel is preserved from corrosion by cathodic protection. Alloying ...
These plaques can flake off, leading to visible impurities in water and a slight metallic taste. The life expectancy of galvanized piping is about 40–50 years, [12] but it may vary on how well the pipes were built and installed. Pipe longevity also depends on the thickness of zinc in the original galvanizing, which ranges on a scale from G01 ...