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In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group (−NO 2) into an organic compound.The term also is applied incorrectly to the different process of forming nitrate esters (−ONO 2) between alcohols and nitric acid (as occurs in the synthesis of nitroglycerin).
Dissolving ammonium nitrate in water is endothermic. The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules.
The golden rain chemical reaction demonstrates the formation of a solid precipitate. The golden rain experiment involves two soluble ionic compounds, potassium iodide (KI) and lead(II) nitrate (Pb(NO 3) 2). They are initially dissolved in separate water solutions, which are each colorless.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In organic chemistry, a nitrate ester is an organic functional group with the formula R−ONO 2, where R stands for any organyl group. They are the esters of nitric acid and alcohols . A well-known example is nitroglycerin , which is not a nitro compound, despite its name.
The reaction, in general, obeys Zaitsev's Rule, which states that the most stable (usually the most substituted) alkene is formed. Tertiary alcohols are eliminated easily at just above room temperature, but primary alcohols require a higher temperature. This is a diagram of acid catalyzed dehydration of ethanol to produce ethylene:
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
In the case of water electrolysis, Gibbs free energy represents the minimum work necessary for the reaction to proceed, and the reaction enthalpy is the amount of energy (both work and heat) that has to be provided so the reaction products are at the same temperature as the reactant (i.e. standard temperature for the values given above ...