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The table values for −100 °C to 100 °C were computed by the following formulas, where T is in kelvins and vapor pressures, P w and P i, are in pascals. Over liquid water. log e (P w) = −6094.4642 T −1 + 21.1249952 − 2.724552×10 −2 T + 1.6853396×10 −5 T 2 + 2.4575506 log e (T)
A Assuming an altitude of 194 metres above mean sea level (the worldwide median altitude of human habitation), an indoor temperature of 23 °C, a dewpoint of 9 °C (40.85% relative humidity), and 760 mmHg sea level–corrected barometric pressure (molar water vapor content = 1.16%). B Calculated values *Derived data by calculation.
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
The dashed green line shows the anomalous behavior of water. For simplicity and clarity, the generic notion of critical point is best introduced by discussing a specific example, the vapor–liquid critical point. This was the first critical point to be discovered, and it is still the best known and most studied one.
Triple points mark conditions at which three different phases can coexist. For example, the water phase diagram has a triple point corresponding to the single temperature and pressure at which solid, liquid, and gaseous water can coexist in a stable equilibrium (273.16 K and a partial vapor pressure of 611.657 Pa).
The Mollier enthalpy–entropy diagram for water and steam. The "dryness fraction", x , gives the fraction by mass of gaseous water in the wet region, the remainder being droplets of liquid. An enthalpy–entropy chart , also known as the H – S chart or Mollier diagram , plots the total heat against entropy, [ 1 ] describing the enthalpy of a ...
The energy level of the bonding orbitals is lower, and the energy level of the antibonding orbitals is higher. For the bond in the molecule to be stable, the covalent bonding electrons occupy the lower energy bonding orbital, which may be signified by such symbols as σ or π depending on the situation.
The calorie is defined as the amount of thermal energy necessary to raise the temperature of one gram of water by 1 Celsius degree, from a temperature of 14.5 °C, at a pressure of 1 atm. For thermochemistry a calorie of 4.184 J is used, but other calories have also been defined, such as the International Steam Table calorie of 4.1868 J .