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On the molecular level, the interlocked molecules cannot be separated without the breaking of the covalent bonds that comprise the conjoined molecules; this is referred to as a mechanical bond. Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, and molecular Borromean rings.
In macromolecular chemistry, a catenane (from Latin catena 'chain') is a mechanically interlocked molecular architecture consisting of two or more interlocked macrocycles, i.e. a molecule containing two or more intertwined rings. The interlocked rings cannot be separated without breaking the covalent bonds of the macrocycles.
In chemistry, molecular Borromean rings are an example of a mechanically-interlocked molecular architecture in which three macrocycles are interlocked in such a way that breaking any macrocycle allows the others to dissociate. They are the smallest examples of Borromean rings.
In chemistry, molecular Borromean rings are the molecular counterparts of Borromean rings, which are mechanically-interlocked molecular architectures. In 1997, biologist Chengde Mao and coworkers of New York University succeeded in constructing a set of rings from DNA. [44]
Rotaxane synthesis can be carried out via a "capping," "clipping, "slipping" or "active template" mechanism. Synthesis via the capping method relies strongly upon a thermodynamically driven template effect; that is, the "thread" is held within the "macrocycle" by non-covalent interactions, for example rotaxinations with cyclodextrin macrocycles involve exploitation of the hydrophobic effect.
Polycatenane model. [1]A polycatenane is a chemical substance that, like polymers, is chemically constituted by a large number of units. [2] These units are made up of concatenated rings into a chain-like structure.
A molecular topology is an area in chemistry that involves different mechanically-interlocked molecular architectures. Pages in category "Molecular topology" The following 14 pages are in this category, out of 14 total.
Examples of molecules for which there exist topoisomers include DNA, which can form knots, and catenanes. Each topoisomer of a given DNA molecule possesses a different linking number associated with it. DNA topoisomers can be interchanged by enzymes called topoisomerases.