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Wavenumber, as used in spectroscopy and most chemistry fields, is defined as the number of wavelengths per unit distance, typically centimeters (cm −1): ~ =, where λ is the wavelength. It is sometimes called the "spectroscopic wavenumber". [1]
where T is the tension force in the string, and μ is the string's mass per unit length. As for the case of electromagnetic waves in vacuum, ideal strings are thus a non-dispersive medium, i.e. the phase and group velocities are equal and independent (to first order) of vibration frequency.
The Planck relation [1] [2] [3] (referred to as Planck's energy–frequency relation, [4] the Planck–Einstein relation, [5] Planck equation, [6] and Planck formula, [7] though the latter might also refer to Planck's law [8] [9]) is a fundamental equation in quantum mechanics which states that the energy E of a photon, known as photon energy, is proportional to its frequency ν: =.
The Planck constant, or Planck's constant, denoted by , [1] is a fundamental physical constant [1] of foundational importance in quantum mechanics: a photon's energy is equal to its frequency multiplied by the Planck constant, and the wavelength of a matter wave equals the Planck constant divided by the associated particle momentum.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
where m is the Bragg order (a positive integer), λ B the diffracted wavelength, Λ the fringe spacing of the grating, θ the angle between the incident beam and the normal (N) of the entrance surface and φ the angle between the normal and the grating vector (K G). Radiation that does not match Bragg's law will pass through the VBG undiffracted.
The Boltzmann constant sets up a relationship between wavelength and temperature (dividing hc/k by a wavelength gives a temperature) with one micrometer being related to 14 387.777 K, and also a relationship between voltage and temperature (kT in units of eV corresponds to a voltage) with one volt being related to 11 604.518 K.
Formally, the wavelength version of Wien's displacement law states that the spectral radiance of black-body radiation per unit wavelength, peaks at the wavelength given by: = where T is the absolute temperature and b is a constant of proportionality called Wien's displacement constant, equal to 2.897 771 955... × 10 −3 m⋅K, [1] [2] or b ...