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The other sodium arsenates are NaH 2 AsO 4 and Na 3 AsO 4, the latter being called sodium arsenate. Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid. [1] Being a diprotic acid, its acid-base properties is described by two equilibria: H 2 AsO − 4 + H 2 O ⇌ HAsO 2−
Sodium arsenate is the inorganic compound with the formula Na 3 AsO 4. Related salts are also called sodium arsenate, including Na 2 HAsO 4 (disodium hydrogen arsenate) and NaH 2 AsO 4 (sodium dihydrogen arsenate). The trisodium salt is a white or colourless solid that is highly toxic. It is usually handled as the dodecahydrate Na 3 AsO 4. 12H ...
Sodium dihydrogen arsenate is a colorless solid that is highly toxic. The salt is the conjugate base of arsenic acid: H 3 AsO 4 ⇌ H 2 AsO − 4 + H + (K 1 = 10 −2.19) In the laboratory, it is prepared in this way, crystallizing from a hot saturated aqueous solution, where it is highly soluble when hot (75.3 g in 100 mL at 100 °C). It is ...
The anhydride 1-arsenato-3-phospho-D-glycerate generated readily hydrolyzes due to the longer bond length of As-O compared to P-O. [40] At the mitochondrial level, arsenate uncouples the synthesis of ATP by binding to ADP in the presence of succinate, thus forming an unstable compound that ultimately results in a decrease of ATP net gain. [40]
Arsenate readily reacts with metals to form arsenate metal compounds. [2] [3] Arsenate is a moderate oxidizer and an electron acceptor, with an electrode potential of +0.56 V for its reduction to arsenite. [4] Due to arsenic having the same valency and similar atomic radius to phosphorus, arsenate shares similar geometry and reactivity with ...
An arsinide, arsanide, dihydridoarsenate(1−) or arsanyl compound is a chemical derivative of arsine, where one hydrogen atom is replaced with a metal or cation. The arsinide ion has formula AsH − 2. It can be considered as a ligand with name arsenido or arsanido. Few chemists study arsanyl compounds, as they are both toxic and unstable. [1]
Both flasks are submerged in a dry ice/acetone cooling bath (−78 °C) the temperature of which is being monitored by a thermocouple (the wire on the left). A cooling bath or ice bath , in laboratory chemistry practice, is a liquid mixture which is used to maintain low temperatures, typically between 13 °C and −196 °C.
A colorful example is cobalt(II) chloride, which turns from blue to red upon hydration, and can therefore be used as a water indicator.. The notation "hydrated compound⋅n H 2 O", where n is the number of water molecules per formula unit of the salt, is commonly used to show that a salt is hydrated.