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"Glacial acetic acid" is a name for water-free acetic acid. Similar to the German name "Eisessig" ("ice vinegar"), the name comes from the solid ice-like crystals that form with agitation, slightly below room temperature at 16.6 °C (61.9 °F). Acetic acid can never be truly water-free in an atmosphere that contains water, so the presence of 0. ...
For example, it reacts with water to form acetic acid; [23] with acetic acid to form acetic anhydride; with ammonia and amines to form ethanamides; [24] and with dry hydrogen halides to form acetyl halides. [25] The formation of acetic acid likely occurs by an initial formation of 1,1-dihydroxyethene, which then tautomerizes to give the final ...
It can be prepared by treating a potassium-containing base such as potassium hydroxide or potassium carbonate with acetic acid: CH 3 COOH + KOH → CH 3 COOK + H 2 O. This sort of reaction is known as an acid-base neutralization reaction. At saturation, the sesquihydrate in water solution (CH 3 COOK·1½H 2 O) begins to form semihydrate at 41.3 ...
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with ...
The hydroxyl value can be calculated using the following equation. Note that a chemical substance may also have a measurable acid value affecting the measured endpoint of the titration. The acid value ( AV ) of the substance, determined in a separate experiment, enters into this equation as a correction factor in the calculation of the hydroxyl ...
The same equation relating the concentrations of acid and base applies. The concept of neutralization is not limited to reactions in solution. For example, the reaction of limestone with acid such as sulfuric acid is also a neutralization reaction. [Ca,Mg]CO 3 (s) + H 2 SO 4 (aq) → (Ca 2+, Mg 2+)(aq) + SO 2− 4 (aq) + CO 2 (g) + H 2 O
For example, the acid may be acetic acid and the salt may be sodium acetate. The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, K a of the acid, and the concentrations of the species in solution. [6]
For example, in the case of acetic acid dissolved in water and forming acetate and hydronium ions, CH 3 CO 2 H + H 2 O ⇌ CH 3 CO − 2 + H 3 O + a proton may hop from one molecule of acetic acid onto a water molecule and then onto an acetate anion to form another molecule of acetic acid and leaving the number of acetic acid molecules unchanged.