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Francium-223 is the most stable isotope, with a half-life of 21.8 minutes, [8] and it is highly unlikely that an isotope of francium with a longer half-life will ever be discovered or synthesized. [22] Francium-223 is a fifth product of the uranium-235 decay series as a daughter isotope of actinium-227; thorium-227 is the more common daughter. [23]
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
The stabilisation of ununennium's valence electron and thus the contraction of the 8s orbital cause its atomic radius to be lowered to 240 pm, [36]: 1729–1730 very close to that of rubidium (247 pm), [5] so that the chemistry of ununennium in the +1 oxidation state should be more similar to the chemistry of rubidium than to that of francium.
The CsFr molecule is predicted to have francium at the negative end of the dipole, unlike all known heterodiatomic alkali metal molecules. Francium superoxide (FrO 2) is expected to have a more covalent character than its lighter congeners; this is attributed to the 6p electrons in francium being more involved in the francium–oxygen bonding. [4]
As a result, element 173 is expected to behave chemically like an alkali metal, and one that might be far more reactive than even caesium (francium and element 119 being less reactive than caesium due to relativistic effects): [90] [19] the calculated ionisation energy for element 173 is 3.070 eV, [91] compared to the experimentally known 3.894 ...
This is especially problematic for francium, which by relativistic calculations can be shown to be less electronegative than caesium, but for which the only value (0.7) in the literature predates these calculations.
Perey named the element francium, after her home country, and it joined the other alkali metals in Group 1 of the periodic table of elements. [3] [7] Francium is the second rarest element (after astatine) — only about 550g exists in the entire Earth's crust at any given time — and it was the last element to be discovered in nature.
Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .