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An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions.
The simplest of molecules is the hydrogen molecule-ion, H 2 +, and the simplest of all the chemical bonds is the one-electron bond. H 2 + is composed of two positively charged protons and one negatively charged electron, which means that the Schrödinger equation for
In such a situation, a force is applied in the direction of motion while the kinetic friction force exactly opposes the applied force. This results in zero net force, but since the object started with a non-zero velocity, it continues to move with a non-zero velocity. Aristotle misinterpreted this motion as being caused by the applied force.
In addition to electronic quantum states, molecules have internal degrees of freedom corresponding to rotational and vibrational motion. At appreciable temperatures, many of these new motional modes are excited, resulting in constant motion as seen above. Molecular physics is the study of the physical properties of molecules and molecular dynamics.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The change of motion of an object is proportional to the force impressed; and is made in the direction of the straight line in which the force is impressed. [ 15 ] : 114 By "motion", Newton meant the quantity now called momentum , which depends upon the amount of matter contained in a body, the speed at which that body is moving, and the ...
Further, for molecules larger than triatomic ones, it is quite common to introduce the harmonic approximation, which approximates the potential energy surface as a quadratic function of the atomic displacements. This gives the harmonic nuclear motion Hamiltonian.
There are two causes of aerodynamic force: [1]: §4.10 [2] [3]: 29 the normal force due to the pressure on the surface of the body; the shear force due to the viscosity of the gas, also known as skin friction. Pressure acts normal to the surface, and shear force acts parallel to the surface. Both forces act locally.