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Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. [1] First proposed by George Hammond in 1955, the postulate states that: [2]
These postulates are all based on basic geometry that can be confirmed experimentally with a scale and protractor. Since the postulates build upon the real numbers, the approach is similar to a model-based introduction to Euclidean geometry. Birkhoff's axiomatic system was utilized in the secondary-school textbook by Birkhoff and Beatley. [2]
The axiomatic foundation of Euclidean geometry can be dated back to the books known as Euclid's Elements (circa 300 B.C.). These five initial axioms (called postulates by the ancient Greeks) are not sufficient to establish Euclidean geometry. Many mathematicians have produced complete sets of axioms which do establish Euclidean geometry.
Based on ancient Greek methods, an axiomatic system is a formal description of a way to establish the mathematical truth that flows from a fixed set of assumptions. Although applicable to any area of mathematics, geometry is the branch of elementary mathematics in which this method has most extensively been successfully applied.
Pasch's axiom — Let A, B, C be three points that do not lie on a line and let a be a line in the plane ABC which does not meet any of the points A, B, C.If the line a passes through a point of the segment AB, it also passes through a point of the segment AC, or through a point of segment BC.
The first systematic approach for synthetic geometry is Euclid's Elements. However, it appeared at the end of the 19th century that Euclid's postulates were not sufficient for characterizing geometry. The first complete axiom system for geometry was given only at the end of the 19th century by David Hilbert. At the same time, it appeared that ...
In other words, the elements of geometry form a system which is not susceptible of extension, if we regard the five groups of axioms as valid. The old axiom V.2 is now Theorem 32. The last two modifications are due to P. Bernays. Other changes of note are: The term straight line used by Townsend has been replaced by line throughout.
Elliptic geometry is an example of a geometry in which Euclid's parallel postulate does not hold. Instead, as in spherical geometry , there are no parallel lines since any two lines must intersect. However, unlike in spherical geometry, two lines are usually assumed to intersect at a single point (rather than two).