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This change in structure is related to the lower density of the liquid phase (1.78 g/cm 3) versus solid aluminium trichloride (2.48 g/cm 3). Al 2 Cl 6 dimers are also found in the vapour phase. At higher temperatures, the Al 2 Cl 6 dimers dissociate into trigonal planar AlCl 3 monomer, which is structurally analogous to BF 3.
Most of the solute does not dissociate in a weak electrolyte, whereas in a strong electrolyte a higher ratio of solute dissociates to form free ions. A weak electrolyte is a substance whose solute exists in solution mostly in the form of molecules (which are said to be "undissociated"), with only a small fraction in the form of ions.
Liquid nitrogen. Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders.
In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a non-liquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to ...
Chemists remove gases from solvents when the compounds they are working on are possibly air- or oxygen-sensitive (air-free technique), or when bubble formation at solid-liquid interfaces becomes a problem. The formation of gas bubbles when a liquid is frozen can also be undesirable, necessitating degassing beforehand.
The noble gases do not react with water, but their solubility in water increases when going down the group. Argon atoms in water appear to have a first hydration shell composed of 16±2 water molecules at a distance of 280–540 pm, and a weaker second hydration shell is found out to 800 pm. Similar hydration spheres have been found for krypton ...
Sparging introduces a gas that has little or no partial pressure of the gas(es) to be removed, and increases the area of the gas-liquid interface, which encourages some of the dissolved gas(es) to diffuse into the sparging gas before the sparging gas escapes from the liquid. Many sparging processes, such as solvent removal, use air as the ...
Here K f is the cryoscopic constant (equal to 1.86 °C kg/mol for the freezing point of water), i is the van 't Hoff factor, and m the molality (in mol/kg). This predicts the melting of ice by road salt. In the liquid solution, the solvent is diluted by the addition of a solute, so that fewer molecules are available to freeze.