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Structural biology is the study of the structural properties of biopolymers. In contrast, most synthetic polymers have much simpler and more random (or stochastic) structures. This fact leads to a molecular mass distribution that is missing in biopolymers.
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...
The tangent construction shown above is rarely used in interpreting the stress-strain curves of metals. However, it is popular for analysis of the tensile drawing of polymers. [4] [5] (since it allows study of the regime of stable necking). It may be noted that, for polymers, the strain is commonly expressed as a “draw ratio”, rather than a ...
Many polymers are copolymers, meaning that they are derived from two different monomers. In the case of condensation polymerizations, the ratio of comonomers is usually 1:1. For example, the formation of many nylons requires equal amounts of a dicarboxylic acid and diamine. In the case of addition polymerizations, the comonomer content is often ...
The reactivity ratio for each propagating chain end is defined as the ratio of the rate constant for addition of a monomer of the species already at the chain end to the rate constant for addition of the other monomer.
The degree of polymerization, or DP, is the number of monomeric units in a macromolecule or polymer or oligomer molecule. [1] [2] [3]For a homopolymer, there is only one type of monomeric unit and the number-average degree of polymerization is given by ¯ ¯ = ¯, where ¯ is the number-average molecular weight and is the molecular weight of the monomer unit.
Polymer morphology is a microscale property that is largely dictated by the amorphous or crystalline portions of the polymer chains and their influence on each other. Microscopy techniques are especially useful in determining these microscale properties, as the domains created by the polymer morphology are large enough to be viewed using modern ...
Before drawing, polymer melt is pushed through a die with a large number of small holes, known as a spinneret. Typically, the fibers are air cooled without any need for curing. If curing is needed, two methods are available: dry and wet spinning. In wet spinning, the polymer is dissolved and extruded through a spinneret into a chemical bath.