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When the carbonation front reaches the steel reinforcements (rebar), the pH of the concrete pore water at the steel surface decreases. At a pH value lower than 10.5, the carbon steel is no longuer passivated by an alkaline pH and starts to corrode (general corrosion). A faster diffusion of oxygen (O
Concrete carbonation can be visually revealed by applying a phenolphthalein solution over the fresh surface of a concrete samples (concrete core, prism, freshly fractured bar). Phenolphthalein is a pH indicator , whose color turns from colorless at pH < 8.5 to pink-fuchsia at pH > 9.5.
Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any direct contact with wet concrete and washed without delay if necessary.
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
High PRF is limited to systems that require close-in performance, like proximity fuses and law enforcement radar. For example, if 30 samples are taken during the quiescent phase between transmit pulses using a 30 kHz PRF, then true range can be determined to a maximum of 150 km using 1 microsecond samples (30 x C / 30,000 km/s).
Acid-neutralizing capacity or ANC in short is a measure for the overall buffering capacity against acidification of a solution, e.g. surface water or soil water.. ANC is defined as the difference between cations of strong bases and anions of strong acids (see below), or dynamically as the amount of acid needed to change the pH value from the sample's value to a chosen different value. [1]
Their addition allows to decrease the water-to-cement ratio of concrete or mortar without negatively affecting the workability of the mixture. It enables the production of self-consolidating concrete and high-performance concrete. The water–cement ratio is the main factor determining the concrete strength and its durability. Superplasticizers ...
The carbon steel of rebars is protected from oxidation by atmospheric oxygen by the high pH of concrete interstitial water. Iron bar surface is passivated as long as the pH value is higher than 10.5. Fresh cement water has a pH of about 13.5 while evolved cement water pH ~ 12.5 is controlled by the dissolution of calcium hydroxide (portlandite).