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The bond-dissociation energy (BDE, D0, or DH°) is one measure of the strength of a chemical bond A−B. It can be defined as the standard enthalpy change when A−B is cleaved by homolysis to give fragments A and B, which are usually radical species. [1][2] The enthalpy change is temperature-dependent, and the bond-dissociation energy is often ...
Apart from the decomposition of N 2 O 5 at high temperatures, it can also be decomposed in carbon tetrachloride CCl 4 at 30 °C (303 K). [20] Both N 2 O 5 and NO 2 are soluble in CCl 4 and remain in solution while oxygen is insoluble and escapes. The volume of the oxygen formed in the reaction can be measured in a gas burette.
In chemistry, bond energy (BE) is one measure of the strength of a chemical bond. It is sometimes called the mean bond, bond enthalpy, average bond enthalpy, or bond strength. [1][2][3] IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature of 298.15 K) for all bonds of the same type ...
The water–gas shift reaction (WGSR) describes the reaction of carbon monoxide and water vapor to form carbon dioxide and hydrogen: CO + H 2 O ⇌ CO 2 + H 2. The water gas shift reaction was discovered by Italian physicist Felice Fontana in 1780. It was not until much later that the industrial value of this reaction was realized.
The Haber process, [1] also called the Haber–Bosch process, is the main industrial procedure for the production of ammonia. [2][3] It converts atmospheric nitrogen (N 2) to ammonia (NH 3) by a reaction with hydrogen (H 2) using a finely divided iron metal catalyst: This reaction is slightly favorable in terms of enthalpy, but is disfavored in ...
In chemistry and thermodynamics, the standard enthalpy of formation or standard heat of formation of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements in their reference state, with all substances in their standard states. The standard pressure value p⦵ = 105 Pa (= 100 kPa = 1 ...
Rate equation. In chemistry, the rate equation (also known as the rate law or empirical differential rate equation) is an empirical differential mathematical expression for the reaction rate of a given reaction in terms of concentrations of chemical species and constant parameters (normally rate coefficients and partial orders of reaction) only ...
For a fuel of composition C c H h O o N n, the (higher) heat of combustion is 419 kJ/mol × (c + 0.3 h − 0.5 o) usually to a good approximation (±3%), [2] [3] though it gives poor results for some compounds such as (gaseous) formaldehyde and carbon monoxide, and can be significantly off if o + n > c, such as for glycerine dinitrate, C 3 H 6 ...