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Poroelasticity is a field in materials science and mechanics that studies the interaction between fluid flow, pressure and bulk solid deformation within a linear porous medium and it is an extension of elasticity and porous medium flow (diffusion equation). [1] The deformation of the medium influences the flow of the fluid and vice versa.
The higher the diffusivity (of one substance with respect to another), the faster they diffuse into each other. Typically, a compound's diffusion coefficient is ~10,000× as great in air as in water. Carbon dioxide in air has a diffusion coefficient of 16 mm 2 /s, and in water its diffusion coefficient is 0.0016 mm 2 /s. [1] [2]
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The density of quartz is around 2.65 g/cm 3 but the dry bulk density of a soil can be less than half that value. Most soils have a dry bulk density between 1.0 and 1.6 g/cm 3 but organic soil and some porous clays may have a dry bulk density well below 1 g/cm 3.
The turbulent Schmidt number is commonly used in turbulence research and is defined as: [3] = where: is the eddy viscosity in units of (m 2 /s); is the eddy diffusivity (m 2 /s).; The turbulent Schmidt number describes the ratio between the rates of turbulent transport of momentum and the turbulent transport of mass (or any passive scalar).
Mass transfer coefficients can be estimated from many different theoretical equations, correlations, and analogies that are functions of material properties, intensive properties and flow regime (laminar or turbulent flow). Selection of the most applicable model is dependent on the materials and the system, or environment, being studied.
In pharmaceutical sciences, tortuosity is used in relation to diffusion-controlled release from solid dosage forms. Insoluble matrix formers, such as ethyl cellulose , certain vinyl polymers, starch acetate and others control the permeation of the drug from the preparation and into the surrounding liquid.
Along with the amount of time the chemical was on the material and the analysis of the test material, one can determine the cumulative permeation of the test chemical. The following table gives examples of the calculated permeability coefficient of certain gases through a silicone membrane.