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In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a real gas or liquid (as differentiated from an ideal gas) when it is expanding; typically caused by the pressure loss from flow through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment.
The Joule–Thomson effect, the temperature change of a gas when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. The Gough–Joule effect or the Gow–Joule effect, which is the tendency of elastomers to contract if heated while they are under tension.
This Thomson effect was predicted and later observed in 1851 by Lord Kelvin (William Thomson). [9] It describes the heating or cooling of a current-carrying conductor with a temperature gradient. If a current density J {\displaystyle \mathbf {J} } is passed through a homogeneous conductor, the Thomson effect predicts a heat production rate per ...
Charles Haldat made some penetrating criticisms of the reproducibility of Rumford's results [15] and it is possible to see the whole experiment as somewhat tendentious. [16] However, the experiment inspired the work of James Prescott Joule in the 1840s. Joule's more exact measurements were pivotal in establishing the kinetic theory at the ...
On the other hand, real-gas models have to be used near the condensation point of gases, near critical points, at very high pressures, to explain the Joule–Thomson effect, and in other less usual cases. The deviation from ideality can be described by the compressibility factor Z.
The Joule expansion, treated as a thought experiment involving ideal gases, is a useful exercise in classical thermodynamics. It provides a convenient example for calculating changes in thermodynamic quantities, including the resulting increase in entropy of the universe ( entropy production ) that results from this inherently irreversible process.
This temperature change is known as the Joule–Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy using statistical mechanics as
James Joule was born in 1818, the son of Benjamin Joule (1784–1858), a wealthy brewer, and his wife, Alice Prescott, on New Bailey Street in Salford. [3] Joule was tutored as a young man by the famous scientist John Dalton and was strongly influenced by chemist William Henry and Manchester engineers Peter Ewart and Eaton Hodgkinson.