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  2. Diabetes in dogs - Wikipedia

    en.wikipedia.org/wiki/Diabetes_in_dogs

    [16] [25] [26] Canine obesity causes the corresponding diabetes in dogs also known as canine diabetes (Hoeing 2014). Secondary diabetes may be caused by use of steroid medications, the hormones of estrus , acromegaly , ( spaying can resolve the diabetes), pregnancy, or other medical conditions such as Cushing's disease .

  3. Electrophilic halogenation - Wikipedia

    en.wikipedia.org/wiki/Electrophilic_halogenation

    Halogenation of benzene where X is the halogen, catalyst represents the catalyst (if needed) and HX represents the protonated base. A few types of aromatic compounds, such as phenol, will react without a catalyst, but for typical benzene derivatives with less reactive substrates, a Lewis acid is required as a catalyst.

  4. Sandmeyer reaction - Wikipedia

    en.wikipedia.org/wiki/Sandmeyer_reaction

    The radical mechanism of the Sandmeyer reaction is supported by the detection of biaryl byproducts. [8] The substitution of the aromatic diazo group with a halogen or pseudohalogen is initiated by a one-electron transfer mechanism catalyzed by copper(I) to form an aryl radical with loss of nitrogen gas.

  5. Haloform reaction - Wikipedia

    en.wikipedia.org/wiki/Haloform_reaction

    In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.

  6. Diabetic ketoacidosis - Wikipedia

    en.wikipedia.org/wiki/Diabetic_ketoacidosis

    Usually, these amounts of insulin are sufficient to suppress ketogenesis. If DKA occurs in someone with type 2 diabetes, their condition is called "ketosis-prone type 2 diabetes". [22] The exact mechanism for this phenomenon is unclear, but there is evidence both of impaired insulin secretion and insulin action.

  7. Hammett equation - Wikipedia

    en.wikipedia.org/wiki/Hammett_equation

    the ionization of substituted phenols in water (+2.008) the acid catalyzed esterification of substituted benzoic esters in ethanol (-0.085) the acid catalyzed bromination of substituted acetophenones (Ketone halogenation) in an acetic acid/water/hydrochloric acid (+0.417) the hydrolysis of substituted benzyl chlorides in acetone-water at 69.8 ...

  8. Hell–Volhard–Zelinsky halogenation - Wikipedia

    en.wikipedia.org/wiki/Hell–Volhard–Zelinsky...

    An example of the Hell–Volhard–Zelinsky reaction can be seen in the preparation of alanine from propionic acid.In the first step, a combination of bromine and phosphorus tribromide is used in the Hell–Volhard–Zelinsky reaction to prepare 2-bromopropionic acid, [3] which in the second step is converted to a racemic mixture of the amino acid product by ammonolysis.

  9. Friedel–Crafts reaction - Wikipedia

    en.wikipedia.org/wiki/Friedel–Crafts_reaction

    The Nencki reaction (1881) is the ring acetylation of phenols with acids in the presence of zinc chloride. [24] In a green chemistry variation aluminium chloride is replaced by graphite in an alkylation of p-xylene with 2-bromobutane. This variation will not work with primary halides from which less carbocation involvement is inferred. [25]