Search results
Results From The WOW.Com Content Network
Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.
Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
[citation needed] This dependence of specific rotation on wavelength is called optical rotatory dispersion. In all materials the rotation varies with wavelength. The variation is caused by two quite different phenomena. The first accounts in most cases for the majority of the variation in rotation and should not strictly be termed rotatory ...
The specific rotation [] is a physical property and defined as the optical rotation α at a path length l of 1 dm, a concentration c of 10 g/L, a temperature T (usually 20 °C) and a light wavelength λ (usually sodium D line at 589.3 nm): [4]
For rotation from the laboratory frame to the local frame, the sign of the sine terms inverts. Linear polarizer (horizontal transmission) The Mueller matrices for other polarizer rotation angles can be generated by reference frame rotation.
The observed rotation of the sample is the weighted sum of the optical rotation of each anomer weighted by the amount of that anomer present. Therefore, one can use a polarimeter to measure the rotation of a sample and then calculate the ratio of the two anomers present from the enantiomeric excess, as long as one knows the rotation of each pure anomer.
Finding the Jones matrix, J(α, β, γ), for an arbitrary rotation involves a three-dimensional rotation matrix. In the following notation α , β and γ are the yaw, pitch, and roll angles (rotation about the z-, y-, and x-axes, with x being the direction of propagation), respectively.
At the end of this memoir he proposed a variation of the experiment, involving a Fresnel rhomb, for the purpose of verifying that optical rotation is a form of birefringence: he predicted that if the compressed glass prisms were replaced by (unstressed) monocrystalline quartz prisms with the same direction of optical rotation and with their ...