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The Flory–Fox equation relates the number-average molecular weight, M n, to the glass transition temperature, T g, as shown below: =, where T g,∞ is the maximum glass transition temperature that can be achieved at a theoretical infinite molecular weight and K is an empirical parameter that is related to the free volume present in the polymer sample.
Lyotropic main chain LCPs have rigid mesogen cores (such as aromatic rings) in the backbones. [12] This type of LCPs forms liquid crystals due to their rigid chain conformation but not only the aggregation of mesogen cores. Because of the rigid structure, strong solvent is needed to dissolve the lyotropic main chain polymers.
The most common applications are in the making of pottery, glass, and some types of food, but there are many others, such as the vitrification of an antifreeze-like liquid in cryopreservation. In a different sense of the word, the embedding of material inside a glassy matrix is also called vitrification. An important application is the ...
Under thermal effect, the end of polymer chain departs, and forms low free radical which has low activity. Then according to the chain reaction mechanism, the polymer loses the monomer one by one. However, the molecular chain doesn't change a lot in a short time. The reaction is shown below. [5] This process is common for polymethymethacrylate ...
Other materials, such as many polymers, lack a well defined crystalline state and easily form glasses, even upon very slow cooling or compression. The tendency for a material to form a glass while quenched is called glass forming ability. This ability depends on the composition of the material and can be predicted by the rigidity theory. [12]
Food contact material pictogram (left) on a plastic food container in Hong Kong. Food contact materials or food contacting substances (FCS) [1] [2] are materials that are intended to be in contact with food. These can be things that are quite obvious like a glass or a can for soft drinks as well as machinery in a food factory or a coffee machine.
Glass-filled polymer (or glass-filled plastic), is a mouldable composite material. It comprises short glass fibers in a matrix of a polymer material. It is used to manufacture a wide range of structural components by injection or compression moulding. [1] It is an ideal glass alternative that offers flexibility in the part, chemical resistance ...
Although food engineering is a relatively recent and evolving field of study, it is based on long-established concepts and activities. [1] The traditional focus of food engineering was preservation, which involved stabilizing and sterilizing foods, preventing spoilage, and preserving nutrients in food for prolonged periods of time. [5]