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  2. Iodine clock reaction - Wikipedia

    en.wikipedia.org/wiki/Iodine_clock_reaction

    Sodium thiosulfate is used to reduce iodine back to iodide before the iodine can complex with the starch to form the characteristic blue-black color. Iodine is generated: 2 I − + S 2 O 2− 8 → I 2 + 2 SO 2− 4. And is then removed: I 2 + 2 S 2 O 2− 3 → 2 I − + S 4 O 2− 6. Once all the thiosulfate is consumed the iodine may form a ...

  3. Iodometry - Wikipedia

    en.wikipedia.org/wiki/Iodometry

    Standard iodine solution is prepared from potassium iodate and potassium iodide, which are both primary standards: IO − 3 + 8 I − + 6 H + → 3 I − 3 + 3 H 2 O. Iodine in organic solvents, such as diethyl ether and carbon tetrachloride, may be titrated against sodium thiosulfate dissolved in acetone. [clarification needed]

  4. Sodium thiosulfate - Wikipedia

    en.wikipedia.org/wiki/Sodium_thiosulfate

    Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula Na 2 S 2 O 3 ·(H 2 O) x. Typically it is available as the white or colorless pentahydrate (x = 5), which is a white solid that dissolves well in water. The compound is a reducing agent and a ligand, and these properties underpin its applications. [2]

  5. Iodine value - Wikipedia

    en.wikipedia.org/wiki/Iodine_value

    12.69 is the conversion factor from mEq sodium thiosulfate to grams of iodine (the molecular weight of iodine is 126.9 g/mol); W is the weight of the sample in grams. The determination of IV according to Wijs is the official method currently accepted by international standards such as DIN 53241-1:1995-05, AOCS Method Cd 1-25, EN 14111 and ISO ...

  6. Tetrathionate - Wikipedia

    en.wikipedia.org/wiki/Tetrathionate

    Tetrathionate is a product of the oxidation of thiosulfate, S 2 O 2− 3, by iodine, I 2: 2 S 2 O 2− 3 + I 2 → S 4 O 2− 6 + 2I −. The use of bromine instead of iodine is dubious as excess bromine will oxidize the thiosulfate to sulfate.

  7. Sodium tetrathionate - Wikipedia

    en.wikipedia.org/wiki/Sodium_tetrathionate

    Sodium tetrathionate is formed by the oxidation of sodium thiosulfate (Na 2 S 2 O 3), e.g. by the action of iodine: [1] 2 Na 2 S 2 O 3 + I 2 → Na 2 S 4 O 6 + 2 NaI. The reaction is signaled by the decoloration of iodine. This reaction is the basis of iodometric titrations. Other methods include the coupling of sodium bisulfite with disulfur ...

  8. Thiosulfate - Wikipedia

    en.wikipedia.org/wiki/Thiosulfate

    Thiosulfate (IUPAC-recommended spelling; sometimes thiosulphate in British English) is an oxyanion of sulfur with the chemical formula S 2 O 2− 3.Thiosulfate also refers to the compounds containing this anion, which are the salts of thiosulfuric acid, such as sodium thiosulfate Na 2 S 2 O 3 and ammonium thiosulfate (NH 4) 2 S 2 O 3.

  9. Iodine–starch test - Wikipedia

    en.wikipedia.org/wiki/Iodine–starch_test

    The cut surface of an apple stained with iodine, indicating a starch level of 4–5. The iodine–starch test is a chemical reaction that is used to test for the presence of starch or for iodine. The combination of starch and iodine is intensely blue-black. [1] [2] The interaction between starch and the triiodide anion (I − 3) is the basis ...

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