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A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
Potentiometric titrations were first used for redox titrations by Crotogino. He titrated halide ions with potassium permanganate using a shiny platinum electrode and a calomel electrode . He said that if an oxidizing agent is added to a reducing solution then the equilibrium between the reducing substance and reaction product will shift towards ...
Inverted logistic S-curve to model the relation between wheat yield and soil salinity. Many natural processes, such as those of complex system learning curves, exhibit a progression from small beginnings that accelerates and approaches a climax over time. When a specific mathematical model is lacking, a sigmoid function is often used.
These approximations are only valid near, but not at, the end point, and so the method differs from end point estimations by way of first- and second-derivative plots, which require data at the end point. Gran plots were originally devised for graphical determinations in pre-computer times, wherein an x-y plot on paper would be manually ...
The classical finite-difference approximations for numerical differentiation are ill-conditioned. However, if is a holomorphic function, real-valued on the real line, which can be evaluated at points in the complex plane near , then there are stable methods.
An illustration of the five-point stencil in one and two dimensions (top, and bottom, respectively). In numerical analysis, given a square grid in one or two dimensions, the five-point stencil of a point in the grid is a stencil made up of the point itself together with its four "neighbors".
For a first-order PDE, the method of characteristics discovers so called characteristic curves along which the PDE becomes an ODE. [ 1 ] [ 2 ] Once the ODE is found, it can be solved along the characteristic curves and transformed into a solution for the original PDE.
To get the coefficients of the backward approximations from those of the forward ones, give all odd derivatives listed in the table in the previous section the opposite sign, whereas for even derivatives the signs stay the same. The following table illustrates this: [5]